N-Bridged bis-amidine N-oxides – a versatile platform in metallosupramolecular chemistry

Abstract

An N-bridged bis-amidine N-oxide (AMOX) ligand was synthesized, characterized, and used as a synthon for AMOX-based supramolecular architectures. Different multimetallic compounds were obtained upon its coordination with transition metal ions: a dinuclear discrete assembly with Ni(II) and a luminescent Zn(II) 1D-metallopolymer, as confirmed by their solid-state structures.

Graphical abstract: N-Bridged bis-amidine N-oxides – a versatile platform in metallosupramolecular chemistry

Supplementary files

Article information

Article type
Communication
Submitted
18 May 2026
Accepted
28 May 2026
First published
10 Jun 2026
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2026, Advance Article

N-Bridged bis-amidine N-oxides – a versatile platform in metallosupramolecular chemistry

M. Lepage, M. Devos, S. Touaibia, G. S. Hanan and M. Cibian, Dalton Trans., 2026, Advance Article , DOI: 10.1039/D6DT01182A

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