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Two mononuclear Ir(I)-corrorin complexes, FPh-Ir and Py-Ir, featuring peripheral κ 2 -N,N′ dipyrrin coordination, were structurally characterized and shown to combine good photostability with efficiently green-light-sensitized singlet oxygen generation (ΦΔ = 0.65-0.69 in CH3CN). TD-DFT supports a nearresonant S1→T3 intersystem-crossing pathway with appreciable spin-orbit coupling.
Y. Wang, Y. Wu, L. Wang, L. Sang, J. Cao, H. Furuta, S. Xue and R. Feng, Dalton Trans., 2026, Accepted Manuscript , DOI: 10.1039/D6DT00801A
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