The first example of azophosphines acting as a bridging ligand between two metal centres is reported. The hemilability of the azophosphine ligand renders the gold(I) dimer formation reversible, so that the complex is not a catalytic dead-end. The catalytic ability of the gold(I) azophosphine complexes is demonstrated through a series of cyclisation reactions that form C-C and C-O bonds.
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E. J. Jordan, B. L. Greene, L. E. English, E. M. Tait, P. Davies and A. R. Jupp, Dalton Trans., 2026, Accepted Manuscript , DOI: 10.1039/D6DT00553E
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