From the journal:

Dalton Transactions

Spin dynamics in RuIII-oxalate complexes: synthesis, characterization, and ab initio insights

Federico Mesa, ORCID logo a   Carolina Pacheco, ORCID logo a   Javier González-Platas, ORCID logo b   Carlos Cruz, ORCID logo c   Verónica Paredes-García, ORCID logo cd   Nicolás Veiga, ORCID logo a   Lorena Martínez ORCID logo a  and  Raúl Chiozzone ORCID logo *a  

* Corresponding authors

a Universidad de la República, Facultad de Química, Área Química Inorgánica, Montevideo, Uruguay
E-mail: rchiozzo@fq.edu.uy

b Universidad de La Laguna, Departamento de Física, Instituto Universitario de Estudios Avanzados en Física Atómica, Molecular y Fotónica (IUDEA), MALTA Consolider Team, La Laguna, Tenerife, Spain

c Center for the Development of Nanoscience and Nanotechnology, CEDENNA, Santiago de Chile, Chile

d Universidad Andrés Bello, Facultad de Ciencias Exactas, Departamento de Ciencias Químicas, Santiago de Chile, Chile

Abstract

Neutral 1D chains [RuCl2(μ-ox)2Ln(H2O)x(dmf)4]n [Ln = La, x = 1 (2); Ln = Dy, x = 0 (3)] were obtained by self-assembly from LnCl3·nH2O and (PPh4)2(H3O)[RuCl2(ox)2]·4H2O (1·4H2O). Compounds 1 and 2 display field-induced slow magnetic relaxation dominated by Raman processes, whereas no such behavior is observed for the Dy-containing chain.

Graphical abstract: Spin dynamics in RuIII-oxalate complexes: synthesis, characterization, and ab initio insights

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Article information

DOI
https://doi.org/10.1039/D6DT00473C
Article type
Communication
Submitted
25 Feb 2026
Accepted
08 Apr 2026
First published
13 Apr 2026

Dalton Trans., 2026, Advance Article

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Spin dynamics in RuIII-oxalate complexes: synthesis, characterization, and ab initio insights

F. Mesa, C. Pacheco, J. González-Platas, C. Cruz, V. Paredes-García, N. Veiga, L. Martínez and R. Chiozzone, Dalton Trans., 2026, Advance Article , DOI: 10.1039/D6DT00473C

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