The carbido complex [Rh2(μ-C)Cl2(μ-dppm)2] reacts with triphenyl cyclopropenium hexafluorophosphate to afford the exo-metallated metallacyclopentadiene salt [Rh2(μ-C4Ph3)Cl2(μ-dppm)2]PF6. via formal insertion of a metal-carbon multiple bond into the cyclopropenium ring.
H. J. Barnett and A. Hill, Dalton Trans., 2026, Accepted Manuscript , DOI: 10.1039/D6DT00300A
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