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This study defines the conditions under which protonated cytosine dimers prevail in nitrocarboxylate salts. X-ray diffraction reveals the solid-state assemblies, calorimetry determines the relevant protonation window, and DFT explains how proton activity, stoichiometry, and hydration stabilize persistent dimers.
O. Książkiewicz, M. Palusiak, Z. Kinart and K. Wzgarda-Raj, Phys. Chem. Chem. Phys., 2026, Accepted Manuscript , DOI: 10.1039/D6CP00954A
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