A case study in borane-catalyzed reaction mechanism of diazo is selected to elucidate the activation mode of such compound. The computational results show that the formation of borane carbene species is the key intermediate for further transformation, which is different from the previous accepted LA-ligated free carbene species.
To support increased transparency, we offer authors the option to publish the peer review history alongside their article.
M. He, H. Yang and Y. Wang, Phys. Chem. Chem. Phys., 2026, Accepted Manuscript , DOI: 10.1039/D6CP00033A
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...
