Unraveling Potassium Segregation in NBT-KBT Single Crystals and its Effect on Structural, Piezoelectric, Dielectric and Ferroelectric Properties

Abstract

The segregation of Potassium ions during the growth of NBT-KBT (Na(1-x)/2 Bi0.5 TiO3 - Kx/2 Bi0.5 TiO3) single crystals via the high-temperature solution growth (self-flux) method presents a significant challenge. In this context, the present study systematically involves the Potassium segregation problem in grown single crystals with varying Potassium content. The poor incorporation of Potassium content in the grown crystals has been confirmed via elemental analysis. Further, a relationship between the initial sodium and Potassium concentrations in the solute and their final composition in the crystal is established. Moreover, the impact of Potassium segregation on the structural, piezoelectric, dielectric and ferroelectric properties of NBT-KBT single crystals is thoroughly investigated. To understand the impact of Potassium substitution, structural transformations were analyzed using line profile analysis and Rietveld refinement. Near the morphotropic phase boundary (MPB), the simultaneous presence of rhombohedral and tetragonal phases was observed, leading to a synergistic enhancement of functional properties such as piezoelectricity, dielectric permittivity, and ferroelectric polarization. Increasing Potassium concentration leads to a rise in the depolarization temperature, implying stronger resistance to thermal depolarization. Notably, near the MPB, the piezoelectric and ferroelectric properties reach their maximum, attributed to the structural phase coexistence and optimized domain configurations. Further, Landau-Devonshire theory describes the temperature-dependent evolution of ferroelectric behavior, where strong and stable polarization is observed at low temperatures. As temperature increases, domain stability weakens, leading to the emergence of ergodic relaxor characteristics, reflected by slimmer P-E loops. These results emphasize the importance of ionic size and domain evolution in enhancing thermal stability and ferroelectric performance of lead-free NKBT piezoelectrics at morphotropic phase boundary. These findings provide an effective approach for growing NBT-KBT single crystals with the desired composition and insights aid in optimizing lead-free piezoelectrics for sensors and actuators applications.