Interface Engineering in Crystalline/Amorphous Pd-Ru Heterostructures for Boosting Alkaline Hydrogen Oxidation Kinetics

Abstract

A crystalline/amorphous Pd–Ru heterostructure is developed for alkaline hydrogen oxidation. Pd nanoclusters decorated on amorphous Ru nanosheets induce an electron-rich heterointerface that concurrently optimizes H* and OH* adsorption, enabling a thermodynamically favorable Volmer step. The catalyst achieves an exchange current density of 5.47 mA cm-2, significantly outperforming both Pd supported on carbon black (Pd/CB) and pure Ru catalysts.

Supplementary files

Article information

Article type
Communication
Submitted
22 Apr 2026
Accepted
08 Jun 2026
First published
08 Jun 2026

Chem. Commun., 2026, Accepted Manuscript

Interface Engineering in Crystalline/Amorphous Pd-Ru Heterostructures for Boosting Alkaline Hydrogen Oxidation Kinetics

J. Wang, X. Zheng, X. Shu, S. Li, J. Wu, C. Wang and L. Kang, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC02472F

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