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A neutral amidophosphine-stabilized Ge(I) dimer 3 featuring a Ge-Ge σ-bond was prepared and structurally characterized. Homolytic dissociation of compound 3 into the neutral monomeric Ge(I) radical in solution was observed, as confirmed by NMR spectroscopy, EPR spectroscopy, and reactivity studies.
Q. Wu, J. Li and H. Wang, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC02286C
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