Fluorinated Zr-MOFs Supported Cu(I) for Synergistic Four-Component CO2 Reactions
Abstract
Through stepwise "ship-in-a-bottle" assembly and "solvent-assisted ligand introduction, CuI-immobilized fluorinated metal-organic frameworks CuI@NU-1000-Fx (x=3, 7, 11) were rationally constructed, which could serves as outstanding candidate in the four-component coupling reaction of alkynes, aldehydes, amines, and CO2 for the preparation of oxazolidinones.
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