Bent Ligand-Directed Assembly and Adsorption Property Modulation of Pseudo-tetrahedral polyoxometalate-organic cages

Abstract

Herein, we present a design strategy for novel pseudo-tetrahedral polyoxovanadate-organic cages employing bent bridging ligands and rigid vanadium clusters. The resulting cage structures exhibit tunable iodine capture capabilities, offering a promising route to porous functional materials with specific architectures.