We report herein a first example of electrochemical ortho-amination of phenols with N-benzoylhydroxylamines. Through a simple undivided cell, a wide range of o-aminophenols can be obtained without any catalyst and base. In addition, the reaction has good functional group tolerance and can be scaled up for production.
C. Deng, H. Han, J. Liu, Z. Zhang, F. Wang and Z. Liu, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC01670G
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