Achieving balanced HER/OER intermediate adsorption is crucial for alkaline water splitting. We report a Mn-doping strategy to reconstruct multimetallic phosphides' active microenvironment, delivering low overpotentials (106 mV HER, 218 mV OER at 10 mA cm -2 ) and stable overall water splitting (1.54 V at 10 mA cm -2 for >100 h).
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H. Yi, W. Yan, F. Qi, Z. Luo, M. Li and C. Wang, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC01537A
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