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The practical synthesis of the bulky arsenide anion, [As(SiiPr3)2]¯, was developed. Then a ylide-like arsasilene LSi(SiiPr3)=AsSiiPr3 (L = PhC(NtBu)2) (2) was synthesized via 1,2-silyl migration of the arsinosilylene LSi-As(SiiPr3)2. Single-electron oxidation of the arsasilene resulted in the formation of aresnic hydride cation via a possible cationic radical intermediate.
J. Wang, Y. Yang, Z. Xiao, M. Zhang and B. Li, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC01524G
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