Metallopolymers and precisely defined oligomers composed of conjugated (bi)phenylene groups linked via BN moieties in 1,3-connectivity pattern to 1’,2’,3’,4’,5’-pentamethylferrocene units are presented. Photophysical studies reveal metal–ligand charge transfer (MLCT) as well as π–π* transitions within the conjugated organic linker with a certain contribution of the 1,3-linked Cp ring.
V. Schütz, J. Kroth, K. Handrup, J. Klopf, A. Friedrich and H. Helten, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC01471B
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