This work employs spectroelectrochemical methods to identify the redox W6+/5+ states responsible for electrochromism from transparent to blue. A correlation of the spectral change with the electron accumulation in the W5+ states has been observed at 0.45 VRHE. This results validate the electrochemical technique for quantification of electrochromic charge transfer.
H. Rong and Y. Ma, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC01218C
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