Fused [5]polynorbornanes are introduced as a new class of rigid aliphatic linker for the synthesis of coordination polymers. Assembly of a 25 Å bis(4-pyridyl) ligand with Zn(II) yielded a non-interpenetrated, uniquely tesselated ladder framework. Gas uptake experiments indicate that this class of linker is a means to access novel porous coordination polymers.
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W. Murrell, D. Coomber, C. Hua, L. Macreadie and F. M. Pfeffer, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC01098A
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