Vanillin-based tetraene monomer (TVE) was synthesized from renewable vanillin via sequential Williamson etherification, followed by atom-economic Claisen rearrangement and Tishchenko condensation. UV-thermal thiol-ene polymerization of TVE yielded bio-based, cross-linked polyester with tunable thermomechanical properties, high transparency, and UV-blocking capability.
Z. Gao, Q. Chen and H. Xie, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC00908E
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