A porous PyC-Zn-MOF which possesses rectangular pore structure and abundant nitrogen/oxygen bifunctional sites is reported. It demonstrated effective separation of CH4/C2H6/C3H8 and CO2/N2 separation, achieves a CH4 purity of > 99.9% with a yield of 7.88 L kg-1 in a single adsorption-desorption cycle, underscoring its outstanding potential for industrial application.
W. Xu, X. Guo, N. Ma, Z. Xing, J. Li and J. Chang, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC00792A
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