VOx/CeMOx catalysts with varying oxygen vacancy formation energy were prepared by doping ceria with 10 first row transition metals. VOx/CeCrOx catalyst with the lowest oxygen vacancy formation energy achieves best aerobic oxidation desulfurization performance. The balance of Ce-O and O-M bond strength is found to be the key point.
X. Tian, S. Huang, Y. Tang, H. Feng, L. Liu, H. Liu and J. Wang, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC00790B
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