Using chiral 4,4′-biphenanthrene-3,3′-diol as ligands, we constructed two pairs of enantiomers of Ln4 cubane clusters: R/S-Dy4 and R/S-Er4. Their enantiopure nature is confirmed by singlecrystal structures and mirrored circular dichroism (CD) spectra. Magnetic studies reveal that R/S-Er4 exhibit field-induced singlemolecule magnet (SMM) behaviour.
H. Qin, T. Wang, T. Feng, Z. Zhu, X. Ying, P. Zhang and J. Tang, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC00777E
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