Phosphinoyl radical generation limits β-ketophosphonate synthesis. We present a photocatalytic method coupling silyl enol ethers with oxime phosphonates. The key radical is efficiently generated via single-electron reduction of oxime phosphonate. The reaction accommodates a wide range of silyl enol ethers, yielding diverse β-ketophosphonates in moderate to good yields.
L. Deng, Z. Zhang, Z. Lin, H. Yang and Q. Chen, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC00706F
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