Beyond FLP additions: FLP deprotonation and C–O bond cleavage of aliphatic, aryl and ester derived olefins

Abstract

Herein, we show that FLP reactivity with alkyl, aryl and ester derived olefins, affording previously unknown C–H deprotonations, 1,4-addition, and C–O bond scissions.

Graphical abstract: Beyond FLP additions: FLP deprotonation and C–O bond cleavage of aliphatic, aryl and ester derived olefins

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Article information

Article type
Communication
Submitted
22 Jan 2026
Accepted
12 Feb 2026
First published
16 Feb 2026

Chem. Commun., 2026, Advance Article

Beyond FLP additions: FLP deprotonation and C–O bond cleavage of aliphatic, aryl and ester derived olefins

A. Goraya, J. McCahill, V. S. Ajithkumar, V. Bedi, K. Ruhlandt and D. W. Stephan, Chem. Commun., 2026, Advance Article , DOI: 10.1039/D6CC00412A

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