The separation of C2H4 and C3H6 is of great significance in the methanol-to-olefin (MTO) process. This study achieved a fluorinated zirconium metal-organic cage-based supramolecular framework, NUT-107, with permanent porosity. This material exhibits high C2H4/C3H6 separation efficiency owing to its suitable pores and binding sites.
T. Yang, Z. Fan, J. Zheng, M. Zhang, Y. Zhou, T. Chen, C. Li, Y. Jiang and L. Sun, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC00359A
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