Herein, we report a manganaelectrooxidative nitrogen atom insertion reaction. Detailed mechanistic studies reveal the crucial roles of manganese–azide intermediates and their anodic oxidation pathway, while a wide range of functional group tolerance demonstrates the practical synthetic utility of this transformation.
M. Jeon, P. K. Jat, J. Baek, G. Kang, J. Kim and I. Choi, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC00221H
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