Few monobenzannulated 1-boraindene compounds have been reported. Here we report the synthesis of two 1-boraindenes, accessed by a bond-breaking and -making cascade from a secondary borane and diolefin, mediated by a simple pentamethylcyclopentadienyl-ligated rhodium(I) complex, [(Cp*)Rh(η2,η2-NBD)] (Cp* = C5Me5-, NBD = norbornadiene).
E. Addison, J. A. Zurakowski, P. D. Boyle, D. J. Nelson and M. W. Drover, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC00158K
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