1,4-dihydropyridine (DHP) anions excited by visible light have been employed as dehalogenation reagents or precursors of formal hydrogen radicals, and enables the sequential dehalogenation (I> Br>Cl) of polyhalogenated compounds. The dehalogenative functionalization reaction was achieved by choice of DHP species and amounts to inhibit the hydrodehalogenation pathway.
X. Zhan, R. Liu, Y. Wang, H. Liu and Y. Peng, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D5CC06847A
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