Dual heterojunction engineering on TiO2 enables the spatial decoupling of active sites, where holes mediate C-H activation and electrons drive O2 activation. This synergistic strategy achieves a remarkable C₂ hydrocarbon production rate of 1.7 mmol g⁻¹ h⁻¹ with 83% selectivity and remarkable 45-hour stability in the photocatalytic oxidative coupling of methane.
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Y. zhou, Y. Wang, Y. Shi, G. Zhao, W. Huang and C. Fu, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D5CC06414G
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