High peak-to-valley ratio in anti-ambipolar organic transistors enabled by two-dimensional molecular crystal heterojunctions

Abstract

We report anti-ambipolar organic field-effect transistors (AA-OFETs) based on two-dimensional molecular crystal (2DMC) p–n heterostructures. Leveraging their ultrathin single-crystalline structure, efficient carrier injection and strong gate modulation, the devices achieve an ultrahigh peak-to-valley ratio of 1.07 × 104.

Graphical abstract: High peak-to-valley ratio in anti-ambipolar organic transistors enabled by two-dimensional molecular crystal heterojunctions

Supplementary files

Article information

Article type
Communication
Submitted
20 Oct 2025
Accepted
01 Dec 2025
First published
01 Dec 2025

Chem. Commun., 2026, Advance Article

High peak-to-valley ratio in anti-ambipolar organic transistors enabled by two-dimensional molecular crystal heterojunctions

J. Yao, X. Shen, X. Wu, H. Xie and R. Li, Chem. Commun., 2026, Advance Article , DOI: 10.1039/D5CC05982H

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