Mechanically interlocked porphyrinoids: self-assembly of metal-stabilised catenaphyrins

Aleksandra Sarwa; Maksym Matviyishyn; Jędrzej P. Perdek; Bartosz Trzaskowski; Dagmara Kulesza; Eugeniusz Zych; Bartosz Szyszko

doi:10.1039/D5CC05702G

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Mechanically interlocked porphyrinoids: self-assembly of metal-stabilised catenaphyrins

Aleksandra Sarwa,

^a Maksym Matviyishyn,

^a Jędrzej P. Perdek,

^a Bartosz Trzaskowski,

^b Dagmara Kulesza,

^a Eugeniusz Zych

^a and Bartosz Szyszko

*^a

Author affiliations

* Corresponding authors

^a Faculty of Chemistry, University of Wrocław, 14 F. Joliot-Curie St., 50-383 Wrocław, Poland
E-mail: bartosz.szyszko@uwr.edu.pl
Web: https://www.bszyszko.pl

^b Centre of New Technologies, University of Warsaw, 2c Banach St., 02-097 Warsaw, Poland

Abstract

Metal-stabilised catenanes comprising two porphyrinoid-like macrocycles were obtained via the self-assembly of bipyrrole and dipyrromethane dialdehydes with bipyridyl-based diamine in the presence of a metal template. Reported architectures exhibited conformational flexibility and distinct photophysical properties, with dipyrrin-based systems displaying strong luminescence.

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DOI: https://doi.org/10.1039/D5CC05702G
Article type: Communication
Submitted: 04 Oct 2025
Accepted: 05 Nov 2025
First published: 05 Nov 2025
This article is Open Access

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Chem. Commun., 2026, Advance Article

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Mechanically interlocked porphyrinoids: self-assembly of metal-stabilised catenaphyrins

A. Sarwa, M. Matviyishyn, J. P. Perdek, B. Trzaskowski, D. Kulesza, E. Zych and B. Szyszko, Chem. Commun., 2026, Advance Article , DOI: 10.1039/D5CC05702G

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Chemical Communications

Mechanically interlocked porphyrinoids: self-assembly of metal-stabilised catenaphyrins

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Mechanically interlocked porphyrinoids: self-assembly of metal-stabilised catenaphyrins

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