Thermodynamic stability and reactivity of amorphised tricalcium silicate

Abstract

Using a model for C–S–H growth kinetics in combination with calorimetry measurements, we show that amorphised tricalcium silicate is more thermodynamically stable than its crystalline form. However, the onset of the hydration reaction occurs more quickly in amorphised tricalcium silicate compared to its crystalline form.

Graphical abstract: Thermodynamic stability and reactivity of amorphised tricalcium silicate

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Article information

Article type
Communication
Submitted
03 Oct 2025
Accepted
15 Dec 2025
First published
23 Dec 2025
This article is Open Access
Creative Commons BY license

Chem. Commun., 2026, Advance Article

Thermodynamic stability and reactivity of amorphised tricalcium silicate

A. T. M. Marsh, T. R. S. Nobre, M. Etchevers, A. Pisch and K. L. Scrivener, Chem. Commun., 2026, Advance Article , DOI: 10.1039/D5CC05691H

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