Deformation-tolerant linkage of silicone rubbers and carbon-based elastomers via chemical and topological adhesion

Abstract

Integrating silicone rubbers with carbon-based elastomers is a common practice in assembling stretchable electronics, but weak or rigid interfacial linkages often lead to structural failure under deformation. Here, we present a chemical and topological adhesive (CTA) composed of poly(styrene–isobutylene–styrene) (SIBS) and maleic anhydride-grafted polypropylene (PP-g-MAH) to bridge silicone rubbers and carbon-based elastomers. The CTA synergizes covalent bonding (via amine-anhydride reactions) with topological entanglement (enabled by matched chain reptation) and achieves interfacial toughness >200 J m−2 through finger-pressing which can be further increased to >600 J m−2 via hot pressing. The adhered interface can endure 10 000 cycles of 100% stretch and 10 days of exposure to acidic/alkaline solutions (pH 1–13). The CTA applies to various silicone rubbers (e.g., polydimethylsiloxane (PDMS) and Ecoflex silicone elastomer) and carbon-based elastomers (e.g., poly(styrene–ethylene–butylene–styrene) (SEBS), poly(styrene–isobutylene–styrene) (SIBS), and poly(styrene–butylene–styrene) (SBS)). This adhesion strategy significantly increases the interfacial toughness of stretchable devices in practical usage, offering a general solution for deformation-tolerant integration of stretchable electronics.

Graphical abstract: Deformation-tolerant linkage of silicone rubbers and carbon-based elastomers via chemical and topological adhesion

Supplementary files

Article information

Article type
Paper
Submitted
22 May 2025
Accepted
08 Jul 2025
First published
10 Jul 2025

J. Mater. Chem. C, 2025, Advance Article

Deformation-tolerant linkage of silicone rubbers and carbon-based elastomers via chemical and topological adhesion

D. Cai and Y. Yu, J. Mater. Chem. C, 2025, Advance Article , DOI: 10.1039/D5TC02022K

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