Anomalous resistivity and superconductivity in the polymorphs of (TiZrHf)95Sc5

Abstract

Three polymorphs of (TiZrHf)95Sc5, one of which is glassy, are identified. The materials are the result of splat cooling arc melted samples. The temperature-dependent resistivities of the body centered cubic and amorphous materials are anomalous. Low temperature resistivity and heat capacity measurements indicate that superconducting transitions are present when the material has either a body centered cubic (TC ∼ 1.5 K) or hexagonal close packed (TC ∼ 0.8 K) crystal structure and the superconductivity of the amorphous phase below 0.65 K cannot be ruled out. We include evidence of a robust critical field in the body centered cubic material.

Graphical abstract: Anomalous resistivity and superconductivity in the polymorphs of (TiZrHf)95Sc5

Article information

Article type
Paper
Submitted
17 Feb 2025
Accepted
04 Jun 2025
First published
25 Jun 2025
This article is Open Access
Creative Commons BY-NC license

J. Mater. Chem. C, 2025, Advance Article

Anomalous resistivity and superconductivity in the polymorphs of (TiZrHf)95Sc5

D. Strong, D. Ni, X. Xu and R. J. Cava, J. Mater. Chem. C, 2025, Advance Article , DOI: 10.1039/D5TC00672D

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