Chicken Egg White Based Amyloid–Graphitic Carbon Nitride Composite Incorporated Hollow Fiber Membrane For Efficient Removal of Dyes And Heavy Metals Present In Water’’

Abstract

Severe water pollution due to excessive industrialization is resulting in pure water crisis for humans and other living beings. This growing crisis emphasizes the urgent need for advanced and efficient water purification technologies to mitigate pollution and ensure the availability of pure water. To address this issue, the current study focuses on synthesis of chicken egg white amyloid-graphitic carbon nitride composite (AM-CN) using graphitic carbon nitride (g-C3N4) and egg whites through environment friendly and simple techniques. These composites were further characterized using different analytical techniques such as BET, FTIR, XRD, SEM, TEM to understand the structure of the composite. Further, these composites were embedded into hollow fiber membranes, and later, these membranes were analyzed through AFM, SEM, and hydrophilicity studies to understand the character and structure of the membrane. The filtration performance of the membrane revealed that the membrane with AM-CN composite demonstrated enhanced performance in both pure water permeability and pollutants removal capacity. Among the fabricated membranes, the neat membrane exhibited a pure water permeability of 81 Lm-2h-1bar-1 whereas the highest permeability of 203 Lm-2h-1bar-1 was exhibited by the M II membrane, therefore considering it as an optimized membrane. This optimized membrane also displayed highest pollutant removal capacity of > 99 % for Congo Red dye, > 98 % for Reactive Black 5 and 88 % for Reactive Orange 16 dye. In the case of heavy metal ion removal, the same membrane displayed an impressive 99% removal of lead ions and 75 % removal of mercury ions in the presence of humic acid.