Additives for Pb defect passivation and FA immobilization: towards efficient and stable perovskite solar cells

Abstract

Perovskite solar cells (Pero-SCs) are rapidly emerging as a promising photovoltaic technology, yet their performance and stability are significantly hampered by defects and ion migration. This work introduces ethyl 4-methyl-2-(4-(trifluoromethyl)phenyl)thiazole-5-carboxylate (EMTC) as a multifunctional additive to mitigate these issues. The trifluoromethyl (-CF3) group of EMTC forms hydrogen bonds with the formamidinium cation (FA+), effectively anchoring it and suppressing ion migration. Simultaneously, the carbonyl (C=O), sulfur (S), and -CF3 groups act as Lewis bases, coordinating with undercoordinated Pb2+ ions. This coordination passivates defects, regulates the perovskite crystallization process, promoting larger grain formation and stabilizing the [PbI6]4− octahedral framework. This controlled crystallization also reduces pathways for organic cation volatilization. Consequently, EMTC-treated devices exhibit a significantly enhanced power conversion efficiency (PCE) from 21.68% to 23.57%. Remarkably, these devices retain over 96% of their initial PCE after 2832 hours of storage under dark, inert (N2) conditions at room temperature, demonstrating significantly improved stability.

Supplementary files

Article information

Article type
Paper
Submitted
22 Jan 2025
Accepted
22 Apr 2025
First published
23 Apr 2025

J. Mater. Chem. A, 2025, Accepted Manuscript

Additives for Pb defect passivation and FA immobilization: towards efficient and stable perovskite solar cells

N. Shao, Q. Chen, R. Tao, W. Yu, X. Nie, W. Ji, Y. Su, Y. Zhou and B. Song, J. Mater. Chem. A, 2025, Accepted Manuscript , DOI: 10.1039/D5TA00615E

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