Photostable triphenylmethyl-based diradicals with a degenerate singlet-triplet ground state and strong photoluminescence

Abstract

We present a new class of luminescent diradicals based on tris(trichlorophenyl)methyl (TTM) cores symmetrically bridged by indolocarbazole donors. These diradicals exhibit pure diradical character y0 and unprecedented photoluminescence quantum yields ϕ of up to 18%, addressing key challenges in the development of stable, emissive organic diradicals. Light emitting diradicals represent a formidable challenge for synthetic chemists; for applications as molecular color centers in quantum sensing and as emitters in optoelectronics. Unlike conventional approaches that require the conversion of closed-shell precursors, we directly couple brominated TTM radicals via Buchwald–Hartwig coupling. The magnetic and optical properties of the resulting molecules are comprehensively characterized by electron paramagnetic resonance EPR, UV-vis absorption, and photoluminescence spectroscopy. This work unites the robust photophysics of discrete TTM radicals with the electronic versatility of donor-bridged multi-spin systems, offering a promising design strategy for functional open-shell emitters.

Graphical abstract: Photostable triphenylmethyl-based diradicals with a degenerate singlet-triplet ground state and strong photoluminescence

Supplementary files

Article information

Article type
Edge Article
Submitted
20 May 2025
Accepted
06 Jul 2025
First published
07 Jul 2025
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2025, Advance Article

Photostable triphenylmethyl-based diradicals with a degenerate singlet-triplet ground state and strong photoluminescence

M. E. Arnold, A. Lebzelter, P. Thielert, R. Blinder, J. Schmid, J. Zolg, E. Spatola, F. Jelezko, M. von Delius, S. Richert and A. J. C. Kuehne, Chem. Sci., 2025, Advance Article , DOI: 10.1039/D5SC03673A

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