Issue 17, 2025

Mesoporous Mo-doped NiCo2O4 nanocrystals for enhanced electrochemical kinetics in high-performance lithium-ion batteries

Abstract

Capacity fading at high rates and a reduced cyclic life due to the deterioration of electrode integrity is one of the major problems in the practical applications of lithium-ion batteries. In this regard, the development of efficient and innovative electrode materials with outstanding transport features and electrochemical properties is urgently needed. In this work, mesoporous Mo-doped NiCo2O4 nanocrystals with enhanced electrochemical kinetics were prepared and investigated as an anode material for lithium-ion batteries. Experimental and density functional theory results demonstrated an increase in the specific surface area, creation of defects and enhanced conductivity. These promising features provide an opportunity to boost the lithium-storage capability of Mo-doped NiCo2O4 nanocrystals. The assembled Mo-doped NiCo2O4 electrode delivered a high initial discharge capacity of 1225 mA h g−1 at 50 mA g−1 and an excellent reversible capacity of ∼512 mA h g−1 at 300 mA g−1 with a coulombic efficiency of about 98%. Moreover, the electrode demonstrated high cyclic stability even after 300 cycles and superior rate performance compared with previously reported electrodes. These results prove that the electrochemically boosted Mo-doped NiCo2O4 structure could be an emerging electrode material for future high-performance batteries.

Graphical abstract: Mesoporous Mo-doped NiCo2O4 nanocrystals for enhanced electrochemical kinetics in high-performance lithium-ion batteries

Supplementary files

Article information

Article type
Paper
Submitted
07 Feb 2025
Accepted
13 Apr 2025
First published
28 Apr 2025
This article is Open Access
Creative Commons BY license

RSC Adv., 2025,15, 13552-13560

Mesoporous Mo-doped NiCo2O4 nanocrystals for enhanced electrochemical kinetics in high-performance lithium-ion batteries

Z. Abbas, T. H. Bokhari, Z. Rana, S. Ijaz, E. Gul, A. Zafar, S. Javaid, M. Gul, K. Maaz, S. Karim, G. Xiang, M. Ahmad and A. Nisar, RSC Adv., 2025, 15, 13552 DOI: 10.1039/D5RA00918A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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