Dearomative 2,3-diamination of indoles triggered by Rh(III)-catalyzed Csp2–H activation

Chengjie Wang; Huanfeng Jiang; Wei Zeng

doi:10.1039/D4QO02017K

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Dearomative 2,3-diamination of indoles triggered by Rh(iii)-catalyzed Csp²–H activation†

Chengjie Wang,^a Huanfeng Jiang

^a and Wei Zeng

*^a

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* Corresponding authors

^a Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, China
E-mail: zengwei@scut.edu.cn

Abstract

An Rh(III)-catalyzed dearomative 2,3-diamination of indoles with N-alkoxyamides has been developed. The method provides an efficient approach to access 2-(N-acylimino)-3-aminoindolines with high regioselectivity.

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Article information

DOI: https://doi.org/10.1039/D4QO02017K
Article type: Research Article
Submitted: 27 Oct 2024
Accepted: 04 Jan 2025
First published: 08 Jan 2025

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Org. Chem. Front., 2025,12, 1821-1826

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Dearomative 2,3-diamination of indoles triggered by Rh(III)-catalyzed Csp²–H activation

C. Wang, H. Jiang and W. Zeng, Org. Chem. Front., 2025, 12, 1821 DOI: 10.1039/D4QO02017K

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