Transition-metal-free reaction of N,N-dialkylanilines with 1-sulfonyl-2-vinylaziridines in hexafluoroisopropanol under air gave ortho-allylated anilines in moderate to excellent yields. The reaction also features mild reaction conditions, ortho-monoallylation selectivity, E-configured C–C double bonds, wide substrate scope and good compatibility of functional groups.
J. Nie and Z. Wang, Org. Chem. Front., 2025, 12, 629 DOI: 10.1039/D4QO01719F
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