Structural optimization of VO2/NH4V4O10 cathode materials for high-performance wide-temperature zinc-ion batteries†
Abstract
Ammonium vanadate is considered as one of the most desirable cathodes for aqueous zinc ion batteries due to its favorable theoretical capacity and open crystal structure. Nevertheless, its further development is still limited by poor structural stability, low electrical conductivity and limited electrolyte compatibility. In this work, we propose a regulation strategy through the pre-introduction of Ce ions. The incorporation of Ce ions increases the interlayer spacing of the host material, which improves the electrical conductivity and accelerates the ion transfer efficiency. The assembled Zn//0.05Ce-VO/NHVO cells deliver an initial capacity of 547.8 mAh g−1 at 0.2 A g−1. They still retain a capacity of 331 mAh g−1 at 5 A g−1 after 4000 cycles. Moreover, the system operates well over a wide temperature range (−20–40 °C). It keeps 92% and 87% capacity retention rates after 1500 cycles at the temperatures of −20 °C and 0 °C, respectively.