A synthesis of the 6–5–5 tricyclic skeleton of the diterpenoid aberrarone is reported. The synthesis strategically features an intermolecular Diels–Alder reaction to construct the cis-hydrindane moiety and a cross-coupling–isomerization–intramolecular Alder–ene cyclization cascade to efficiently assemble the 6–5–5 tricyclic skeleton of aberrarone.
G. Sui, X. Song, H. Guo, X. Xie, L. Ren, W. Zhou and H. Hao, Org. Biomol. Chem., 2025, Advance Article , DOI: 10.1039/D5OB00644A
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