A novel palladium-catalyzed allylic C–H alkylation of terminal olefins with 3-carboxamide oxindoles is described. A variety of new 3-carboxamide-3-allylation oxindoles with an all-carbon quaternary center were obtained in moderate to good yields (up to 99%). In addition, the asymmetric version of this reaction was also explored, providing moderate enantioselectivity.
N. Zhang, G. Liang, D. Zhang, G. Liu, X. Liu, P. Zhou, D. Zhang, H. Zhou and J. Zhou, Org. Biomol. Chem., 2025, 23, 1828 DOI: 10.1039/D4OB01991A
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