Optically/Electrically Controlled Ag+ Metallization in Solution-Processed Oxide Memtransistors for Neuromorphic Computing

Abstract

In this work, a solution-processable oxide-based memtransistor is designed for neuromorphic computing, incorporating LiInSnO₄ as the gate dielectric, SnO₂ as the semiconducting channel, and Ag⁺-exchanged LiV₃O₈ as the resistive switching medium. The device demonstrates dual tunability in its channel conductance, through both gate voltage and light modulation, enabling precise control over its switching characteristics. Operating at low voltages, the memtransistor achieves a LRS/HRS ratio of up to 10³, with stable performance across 10³ switching cycles, over 106 pulse cycles, and retention up to 10⁵ seconds. The device effectively replicates essential synaptic functions such as paired-pulse facilitation, short- and long-term plasticity, with ultra-low energy consumption: 193 pJ (0.1 fJ/μm²) optically and 540 pJ (0.3 fJ/μm²) electrically. It also shows low non-linearity in potentiation/depression events, 0.49/3.47 (optical) and 0.03/5.67 (electrical), facilitating accurate synaptic weight modulation. Light-driven logic operations and cognitive functions, learning, forgetting, and relearning are successfully demonstrated, along with Pavlovian classical conditioning. Neural network simulations confirm 98%and 95% recognition accuracy for optical and electrical synapse, while autoencoder-based denoising and data reconstruction further validate the device's applicability in brain-inspired computing.