Issue 18, 2025
From the journal:

New Journal of Chemistry

Pd-catalyzed hydroesterification of 1,1-disubstituted terminal olefins with aryl formates†

Junhua Li, ORCID logo a   Yaqian Min,a   Tianci Shen,a   Yan Yang,a   Fengyin Wanga  and  Yian Shi ORCID logo *a  

* Corresponding authors

a Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, School of Petrochemical Engineering, Institute of Natural and Synthetic Organic Chemistry, Changzhou University, Changzhou 213164, P. R. China
E-mail: shiyian@cczu.edu.cn

Abstract

A variety of 1,1-disubstituted terminal olefins can be efficiently hydroesterified with Pd(OAc)2-DPEphos and aryl formates to give the corresponding carboxylic esters bearing various functional groups in good yields. The reaction process is operationally simple and requires no handling of toxic CO gas or strong acid.

Graphical abstract: Pd-catalyzed hydroesterification of 1,1-disubstituted terminal olefins with aryl formates

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Article information

DOI
https://doi.org/10.1039/D5NJ00149H
Article type
Paper
Submitted
11 Jan 2025
Accepted
19 Mar 2025
First published
24 Mar 2025

New J. Chem., 2025,49, 7642-7646

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Pd-catalyzed hydroesterification of 1,1-disubstituted terminal olefins with aryl formates

J. Li, Y. Min, T. Shen, Y. Yang, F. Wang and Y. Shi, New J. Chem., 2025, 49, 7642 DOI: 10.1039/D5NJ00149H

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