Tuning charge density waves and magnetic switching in carbon nanowires encased in boron nitride nanotubes

Abstract

The emergence of exotic charge density waves (CDW) alongside ferrimagnetic materials opens exciting new possibilities for quantum switching, particularly in field-tuning CDW electronics. However, these two phenomena often compete and rely heavily on strong electronic correlations. While carbon nanowire arrays have been experimentally shown to exhibit ferromagnetism above 400 K, our research shows that encapsulating a linear carbon chain (LCC) within zigzag boron nitride nanotubes (BNT) induces a short-range CDW state under the competing effect of ferrimagnetism and magnetic frustrations. However, for this exotic phenomenon to occur, the LCC needs to break the symmetry along the circular plane of the BNT. Then we utilize a Monte Carlo model to identify the cut-off length of LCC@BNT to tackle its size effect, while also comparing the stability of chains provided by carbon nanotubes. The shorter LCC@BNT displays a more prominent long-range CDW pattern with a tunneling barrier of 2.3 eV on the Fermi surface, transitioning into an insulator. Meanwhile, magnetic frustrations disappear, and ferrimagnetism remains stable up to 280 K. Our discovery of ferrimagnetic CDW carbyne insulators, which function without conventional periodic lattice distortion, spin–orbit coupling, heavy elements, or complex d and f hybridization represents a groundbreaking shift in thinking, which demonstrates that such exotic properties are not exclusive to transition metal elements.

Graphical abstract: Tuning charge density waves and magnetic switching in carbon nanowires encased in boron nitride nanotubes

Supplementary files

Article information

Article type
Communication
Submitted
10 Apr 2025
Accepted
04 Jul 2025
First published
05 Jul 2025

Mater. Horiz., 2025, Advance Article

Tuning charge density waves and magnetic switching in carbon nanowires encased in boron nitride nanotubes

C. H. Wong, Z. Guo, K. C. Lam, C. P. Chau, W. Y. Chan, C. Tang, Y. H. Tsang, L. Y. F. Lam and X. Hu, Mater. Horiz., 2025, Advance Article , DOI: 10.1039/D5MH00664C

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