Difunctionalization of olefins is effective to construct diverse valuable molecules. However, such reaction always relies on catalysts to control activity and selectivity. Herein, a catalyst-free difunctionalization of olefins with sulfonyl, alkyl precursors and 1,2-dicarbonyls is reported to synthesize complex α-hydroxycarbonyls under visible light irradiation.
H. Hou, Y. Cheng, X. Zhang, K. Zhang, H. Ren, K. Su, Z. Huang, B. Chen, C. Tung and L. Wu, Green Chem., 2025, Accepted Manuscript , DOI: 10.1039/D5GC02308D
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