Synthesis and characterization of stable nickel(ii) complexes bearing long alkyl chains

Abstract

Nickel(II) complexes bearing long alkyl chains are successfully obtained as stable solids by ethylene oligomerization using a Shell Higher Olefin Process (SHOP)-type anionic bidentate (P–O) ligand. In contrast to the salient stability of the alkyl-Ni(II) complexes in the solid state, their chemical derivatization implied the occurrence of non-negligible chain-transfer during the ethylene oligomerization process.

Graphical abstract: Synthesis and characterization of stable nickel(ii) complexes bearing long alkyl chains

Supplementary files

Article information

Article type
Paper
Submitted
19 May 2025
Accepted
16 Jul 2025
First published
17 Jul 2025

Faraday Discuss., 2025, Advance Article

Synthesis and characterization of stable nickel(II) complexes bearing long alkyl chains

Y. Miyake, K. Masada and K. Nozaki, Faraday Discuss., 2025, Advance Article , DOI: 10.1039/D5FD00083A

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