A series of three isomeric double-cavity discrete coordination cages with Pd 3 L 4 formulation, constructed from Pd(II) and regioisomeric tris-monodentate ligands, are compared for binding of pyrazine N,N'-dioxide. Two of the isomeric cages efficiently encapsulated the guest in both cavities whereas one of the isomers rejected the guest completely.
A. Kumar, S. Krishnaswamy and D. K. Chand, Dalton Trans., 2025, Accepted Manuscript , DOI: 10.1039/D5DT02147B
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