The first definitive isolation of phosphaza-norbornanes is reported. These PN frameworks feature a bicyclo[2.2.1]heptane skeleton with bridgehead P(III) sites and can be made via a modular condensation reaction starting from primary amines. Their molecular and electronic structures, stability, and strain energies are compared with closely related PN or hydrocarbon bicyclic systems.
J. Nazak, M. A. Land, J. D. Masuda and S. S. Chitnis, Dalton Trans., 2025, 54, 15020 DOI: 10.1039/D5DT02134K
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